SUMMARY OF PM7 CALCULATION, Site No: 23746 MOPAC2016 (Version: 21.053M) Tue Feb 23 04:25:19 2021 No. of days remaining = 364 Empirical Formula: As8 Cl24 = 32 atoms MERS=(1,2,1) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Arsenic(iii) chloride (AsCl3) h=-73 hr=guess GEOMETRY OPTIMISED USING EIGENVECTOR FOLLOWING (EF). SCF FIELD WAS ACHIEVED HEAT OF FORMATION = -772.87959 KCAL/MOL = -3233.72820 KJ/MOL H.o.F. per unit cell = -96.60995 KCAL, for 8 unit cells, unit cell = As1 Cl3 TOTAL ENERGY = -7456.20672 EV ELECTRONIC ENERGY = -20763357.40522 EV CORE-CORE REPULSION = 20755901.19851 EV VOLUME OF UNIT CELL = 320.822 CUBIC ANGSTROMS DENSITY = 3.753 GRAMS/CC A = 7.676 ANGSTROMS B = 3.851 ANGSTROMS C = 10.968 ANGSTROMS ALPHA = 90.028 DEGREES BETA = 90.190 DEGREES GAMMA = 98.356 DEGREES VOLUME OF CLUSTER = 641.64348 ANGSTROMS**3 = 386.406 CM**3/MOLE GRADIENT NORM = 4.45013 = 0.78668 PER ATOM NO. OF FILLED LEVELS = 104 IONIZATION POTENTIAL = 9.018599 EV HOMO LUMO ENERGIES (EV) = -9.019 -2.411 MOLECULAR WEIGHT = 1450.2448 Pressure required to constrain translation vectors Tv( 33) Pressure: 0.02 GPa Tv( 34) Pressure: -0.00 GPa Tv( 35) Pressure: 0.01 GPa SCF CALCULATIONS = 9 WALL-CLOCK TIME = 8 MINUTES AND 9.560 SECONDS COMPUTATION TIME = 8 MINUTES AND 5.961 SECONDS FINAL GEOMETRY OBTAINED MERS=(1,2,1) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Arsenic(iii) chloride (AsCl3) h=-73 hr=guess As -0.47144477 +1 1.84371735 +1 0.17799017 +1 As 0.59817047 +1 -4.93249598 +1 -0.07820030 +1 As -3.23761838 +1 -3.77437207 +1 0.65094508 +1 Cl -2.93551291 +1 -0.62728896 +1 2.76857561 +1 Cl -1.65355166 +1 1.18119339 +1 -1.80138237 +1 Cl -0.54376383 +1 -6.83592290 +1 -0.83502478 +1 Cl -2.03695646 +1 -3.51658978 +1 2.70533156 +1 Cl -2.57980123 +1 2.40285599 +1 1.13956601 +1 Cl 0.70119068 +1 -1.11226249 +1 -1.64377458 +1 Cl 0.92831158 +1 -3.42917197 +1 3.71319584 +1 Cl -4.20413078 +1 -5.90797749 +1 3.48065157 +1 Cl -4.96412744 +1 2.17433182 +1 3.07973174 +1 Cl -0.45776366 +1 -0.21959950 +1 0.96432712 +1 Cl 1.92629655 +1 -3.15503866 +1 0.79932822 +1 Cl -3.04858054 +1 -5.97236446 +1 0.72329110 +1 As -4.22400248 +1 0.74274021 +1 1.36217071 +1 As 1.91204876 +1 1.33814734 +1 3.69537136 +1 As 0.97725494 +1 -5.59439098 +1 4.10211979 +1 As -3.01825904 +1 -4.26200122 +1 4.73823044 +1 Cl -1.00087077 +1 0.40829271 +1 7.06797886 +1 Cl 0.34944915 +1 2.59441784 +1 2.35655236 +1 Cl 0.02503832 +1 -6.15991445 +1 1.95513664 +1 Cl -1.60563032 +1 -2.46847862 +1 5.49957791 +1 Cl -2.13126528 +1 2.16391872 +1 4.43088685 +1 Cl 2.69324741 +1 -0.47907296 +1 2.38416603 +1 Cl 1.32285472 +1 -1.92986142 +1 6.62122892 +1 Cl -3.65240931 +1 -5.45584154 +1 6.68397659 +1 Cl -3.18681206 +1 3.47221690 +1 7.03811455 +1 Cl 0.27417701 +1 -0.29791513 +1 3.97800412 +1 Cl 3.76059979 +1 -2.69414159 +1 4.90493025 +1 Cl -1.24067625 +1 -5.73415677 +1 5.09310023 +1 As -1.96329466 +1 0.01654769 +1 4.88323063 +1 Tv 6.81503207 +1 -0.40227831 +1 -3.50938772 +1 Tv 2.49832786 +1 1.52300498 +1 7.12557231 +1 Tv -0.50194692 +1 10.74826277 +1 -2.12718062 +1